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关于碳纳米管论文范文写作 氧化多壁碳纳米管、PEGPVP添加剂对PVDF膜性能影响相关论文写作资料

主题:碳纳米管论文写作 时间:2024-02-09

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碳纳米管论文参考文献 低碳旅游论文低碳经济论文低碳论文低碳生活论文

Abstract:Introducing hydrophilic additives is an effective method to improve the structure and permeation performance of polyvinylidene fluoride (PVDF) membranes.In this work,oxidized multiwall carbon nanotubes (OMWNTs) accompanied with polyethylene glycol/polyvinyl pyrrolidone (PEG/PVP) additives were employed to modify PVDF membranes.The effects of additives on the structure,permeation performances,hydrophilicity and crystallization behavior of the prepared PVDF membranes were investigated in detail.The results indicate that the addition of OMWNTs can enhance the permeation flux,hydrophilicity and mechanical property of PVDF membranes.The pure water flux(PWF) attains 222.9±12.5 L·m-2·h-1·bar-1 and 256.9±14.8 L·m-2·h-1·bar-1 by adding 0.6 wt.% OMWNTs accompanied with 5% PEG 200 and 3% PVP in the cast solution,respectively.PEG200 additive can enhance the dispersion of OMWNTs,and accelerate the exchange rate between solvent and nonsolvent.PVP working as poreforming agent promotes the growth of pores of PVDF membranes and pure water permeation flux.

Key words:polyvinylidene fluoride (PVDF) membrane; ultrafiltration; multiwall carbon nanotubes (MWNTs)

CLC number: TQ 31 Document code: A Article ID: 10005137(2016)01004109

1 Introduction

In the recent years,polyvinylidene fluoride (PVDF) has become a very popular material to prepare microfiltration/ultrafiltration(MF/UF) membranes for its superior thermal,chemical stability and oxidation resistance etc.[1-4].However,due to its strong hydrophobicity,PVDF membranes are easily fouled by natural organic matters (NOMs),proteins and other substances.To overcome the shortcomings,various ways were explored to modify PVDF membranes.Among these methods,blending modification is widely used because it makes preparation and modification be accomplished in a single step.And numerous nanofillers were employed to modify PVDF membranes[5-8].

For its high specic surface area,high chemical stability and easy possessing property,multiwall carbon nanotubes (MWNTs) also attracted considerable attentions in membrane field[9].Zhao et al.[10]successfully prepared PVDF/MWNTs membranes and the blending membranes exhibited improved hydrophilicity,pure permeation flux(PWF) and higher bovine serum albumin (BSA) rejection.Ma et al.[11]investigated the effects of oxidized MWNTs (OMWNTs) on PVDF membranes and found that oxygencontaining groups of OMWNTs played a critical role in determining the morphologies and performances of PVDF membranes.However,there are two important issues to retard the application of MWNTs in polymer composites[12].First,it tends to aggregate in the casting solution due to the strong Vander Waals forces.Moreover,smooth surface of CNTs and lack of interfacial bonding will result in weak interfacial adhesion between CNTs and polymer matrix[13].So,lots of works were done to enhance the dispersion and interfacial adhesion[14-16].

结论:适合碳纳米管论文写作的大学硕士及相关本科毕业论文,相关碳纳米管价格开题报告范文和学术职称论文参考文献下载。

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